Tokyo Tech News
Tokyo Tech News
Published: July 22, 2019
A team of researchers from Tokyo Tech has gained unprecedented insight into the inner workings of an atomic switch1. By investigating the composition of the tiny metal ‘bridge' that forms inside the switch, their findings may spur the design of atomic switches with improved performance.
Figure 1. Conceptual image of a metallic filament inside an atomic switch
The ‘bridge’ that forms within the metal sulfide layer, connecting two metal electrodes, results in the atomic switch being turned on.
Atomic switches are hailed as the tiniest of electrochemical switches that could change the face of information technology. Due to their nanoscale dimensions and low power consumption, they hold promise for integration into next-generation circuits that could drive the development of artificial intelligence (AI) and Internet of Things (IoT) devices.
Although various designs have emerged, one intriguing question concerns the nature of the metallic filament, or bridge, that is key to the operation of the switch. The bridge forms inside a metal sulfide layer sandwiched between two electrodes (see Figure 1), and is controlled by applying a voltage that induces an electrochemical reaction. The formation and annihilation of this bridge determines whether the switch is on or off.
Now, a research group including Akira Aiba, Manabu Kiguchi and colleagues at Tokyo Institute of Technology's Department of Chemistry has found a useful way to examine precisely what the bridge is composed of.
By cooling the atomic switch enough so as to be able to investigate the bridge using a low-temperature measurement technique called point contact spectroscopy (PCS) 2, their study revealed that the bridge is made up of metal atoms from both the electrode and the metal sulfide layer. This surprising finding controverts the prevailing notion that the bridge derives from the electrode only, Kiguchi explains.
The team compared atomic switches with different combinations of electrodes (Pt and Ag, or Pt and Cu) and metal sulfide layers (Cu2S and Ag2S). In both cases, they found that the bridge is mainly composed of Ag.
The reason behind the dominance of Ag in the bridge is likely due to "the higher mobility of Ag ions compared to Cu ions", the researchers say in their paper published in ACS Applied Materials & Interfaces.
They conclude that "it would be better to use metals with low mobility" for designing atomic switches with higher stability.
Much remains to be explored in the advancement of atomic switch technologies, and the team is continuing to investigate which combination of elements would be the most effective in improving performance.
The idea behind an atomic switch — one that can be controlled by the motion of a single atom — was introduced by Donald Eigler and colleagues at the IBM Almaden Research Center in 1991. Interest has since focused on how to realize and harness the potential of such extremely small switches for use in logic circuits and memory devices. Over the past two decades, researchers in Japan have taken a world-leading role in the development of atomic switch technologies.
A method of measuring the properties or excitations of single atoms at low temperature.
Reference
Authors : |
A. Aiba1, R. Koizumi1, T. Tsuruoka2, K. Terabe2, K. Tsukagoshi2, S. Kaneko1, S. Fujii1, T. Nishino1, M. Kiguchi1 |
Title of original paper : |
Investigation of Ag and Cu Filament Formation Inside the Metal Sulfide Layer of an Atomic Switch Based on Point-Contact Spectroscopy |
Journal : |
ACS Applied Materials & Interfaces (2019) |
DOI : |
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Affiliations : |
1Department of Chemistry, School of Science, Tokyo Institute of Technology 2International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS) |
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Further Information
Professor Manabu Kiguchi
School of Science, Tokyo Institute of Technology
Email kiguti@chem.titech.ac.jp
Tel +81-3-5734-2071
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