Getting through the bottleneck—A new class of layered perovskite with high oxygen-ion conductivity

Research

Published: April 27, 2020

Scientists at the Tokyo Institute of Technology (Tokyo Tech) have discovered a layered perovskite that shows unusually high oxide-ion conductivity, based on a new screening method and a new design concept. Such materials are hard to come by, so the discovery of this material, the new method and design concept will make the realization of many environment-friendly technologies.

Figure 1. The mechanism, design concept, and structural characteristics that afford high oxide-ion conductivity in CsBi₂Ti₂NbO_10-δ
(a) The oxide-ion conductivity of CsBi₂Ti₂NbO_10-δ is higher than those of many materials reported previously. (b) By screening sixty-nine potential materials using the bond-valence method, CsBi₂Ti₂NbO_10-δ was selected. A new design concept for its high oxide-ion conductivity is proposed: enlarged bottlenecks. (c) Structure of CsBi₂Ti₂NbO_10-δ (left) and the bond-valence-based energy landscape for an oxide ion at 0.6 eV (right), which marks all the possible oxide-ion migration paths. The bottlenecks for oxide-ion migration are enlarged in CsBi₂Ti₂NbO_10-δ.

Upon hearing the word "conductor" in reference to chemistry, most will immediately think of the movement of electrons within a material. But electrons are not the only particles that can move across a material; oxide ions can too. Many materials scientists and engineers are currently searching for materials with high oxide-ion conductivity. Such materials have many potential applications, particularly in the development of environmentally friendly technologies. For example, oxide-ion conductors could be used in fuel cells, which directly convert clean fuel such as hydrogen into electrical energy, or in oxygen separation membranes, which could be useful in systems for capturing the CO₂ we produce by burning coal or fossil fuels.

Unfortunately, high oxide-ion conductivities can be achieved by a limited number of structure families of materials. The perovskites are one such structure family. Perovskites and layered perovskites have special crystal structures that sometimes exhibit outstanding physical and chemical properties. Prof. Masatomo Yashima and colleagues from the Tokyo Institute of Technology studied a class of layered perovskites, a Dion–Jacobson phase, where two-dimensional perovskite-like "slabs" are stacked and separated by a layer of alkali metal ions, such as the cesium cation (Cs⁺). In their paper published in Nature Communications , Professor Yashima and his colleagues explain their motivation: "Numerous studies have been conducted on the electrical properties of Dion–Jacobson phases, such as their proton, lithium-ion and sodium-ion conduction. However, there are no reports on the oxide-ion conduction in Dion–Jacobson phases."

In their study, the scientists first screened sixty-nine potential Dion–Jacobson phases using the bond-valence method. This method allowed them to calculate the energy barriers for oxide-ion migration in each Dion–Jacobson phase, from which they identified CsBi₂Ti₂NbO_10-δ (CBTN) as a promising candidate because it has a low energy barrier and does not contain expensive rare-earth elements. Further, they prepared CBTN samples and found that the oxide-ion conductivity of CBTN was higher than those of many other oxide-ion conductors, such as the conventional yttria-stabilized zirconia (Figure 1).

To understand what causes such high oxide-ion conductivity in CBTN, the scientists analyzed its crystal structure and watched how the structure changes with temperature. Using a super-high-resolution neutron diffractometer, SuperHRPD at J-PARC, they then identified several possible paths across the crystal lattice through which oxide ions could migrate at high temperatures (Figure 1c). Most importantly, they discovered a novel mechanism that seems to be one of the causes of the high oxide-ion conductivity: Rise in temperature makes oxygen vacancies appear, which facilitate oxide-ion migration. The large Cs cations and the displacement of the Bi ions in the structure at high temperatures expand the bottlenecks, enabling oxide-ion migration.

This study paves the way for finding inexpensive novel oxide-ion conductors. Based on this oxide-ion conduction mechanism, one can enhance the oxide-ion conductivities of materials of the CBTN family by modifying the chemical composition of CBTN through the addition of impurities (doping). "The present findings of high oxide-ion conductivity in this new structure family, the Dion–Jacobson-type CsBi₂Ti₂NbO_10-δ, and the new enlarged bottleneck concept introduced, could facilitate the design of novel oxide-ion conductors based on Dion–Jacobson phases," Prof. Yashima and his colleagues conclude. The findings of this study open up the possibilities for many novel applications that will lead to a sustainable future. In fact, the present work was chosen as Editors' Highlights of Nature Communications.

Reference

Authors :	Wenrui Zhang¹, Kotaro Fujii¹, Eiki Niwa¹, Masato Hagihala^2,3, Takashi Kamiyama^2,3 and Masatomo Yashima^*1
Title of original paper :	Oxide-Ion Conduction in the Dion-Jacobson Phase CsBi₂Ti₂NbO_10-δ
Journal :	Nature Communications
DOI :	10.1038/s41467-020-15043-z
Affiliations :	¹ Department of Chemistry, School of Science, Tokyo Institute of Technology ² Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK) ³ Japan Proton Accelerator Research Complex (J-PARC)